{"id":12298,"date":"2024-03-31T00:08:45","date_gmt":"2024-03-30T16:08:45","guid":{"rendered":"http:\/\/www.meiqiyj.com\/?p=12298"},"modified":"2024-03-31T00:08:45","modified_gmt":"2024-03-30T16:08:45","slug":"%e9%93%81%e7%b2%89%e7%bd%ae%e6%8d%a2%e7%a1%ab%e4%bb%a3%e7%a1%ab%e9%85%b8%e9%93%b6%e7%a2%98%e5%8c%96%e9%93%b6%e4%b8%8e%e9%93%81%e7%b2%89%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"http:\/\/www.meiqiyj.com\/newcenter\/zhtfnews\/12298.html","title":{"rendered":"\u94c1\u7c89\u7f6e\u6362\u786b\u4ee3\u786b\u9178\u94f6,\u7898\u5316\u94f6\u4e0e\u94c1\u7c89\u53cd\u5e94"},"content":{"rendered":"

\u94c1\u7c89\u7f6e\u6362\u786b\u4ee3\u786b\u9178\u94f6\u76ee\u5f55<\/p>\n

\u94c1\u7c89\u7f6e\u6362\u786b\u4ee3\u786b\u9178\u94f6<\/a><\/p>\n

\u7898\u5316\u94f6\u4e0e\u94c1\u7c89\u53cd\u5e94<\/a><\/p>\n

\u94c1\u7c89\u4e0e\u786b\u7c89\u53cd\u5e94\u65b9\u7a0b\u5f0f<\/a><\/p>\n

\u786b\u9178\u94f6\u600e\u4e48\u7f6e\u6362\u6210\u5355\u8d28\u94f6<\/a><\/p>\n

\u94c1\u7c89\u7f6e\u6362\u786b\u4ee3\u786b\u9178\u94f6<\/h2>\n

<\/p>\n

\u73af\u4fdd\u7684\u5316\u5b66\u53cd\u5e94\u3002<\/p>\n

\u94c1\u7c89\u7f6e\u6362\u786b\u786b\u9178\u94f6(Fe\/S)\u662f\u4e00\u79cd\u5e38\u89c1\u7684\u5316\u5b66\u53cd\u5e94\u3002\u56e0\u4e3a\u5b83\u80fd\u5927\u91cf\u51cf\u5c11\u5e9f\u5f03\u7269\u7684\u4ea7\u751f\uff0c\u8fd9\u79cd\u53cd\u5e94\u65b9\u5f0f\u5728\u73af\u5883\u4fdd\u62a4\u65b9\u9762\u5177\u6709\u91cd\u8981\u610f\u4e49\uff0c\u540c\u65f6\u8fd8\u80fd\u6709\u6548\u6d88\u9664\u6709\u6bd2\u6709\u5bb3\u7269\u8d28\u3002\u672c\u6587\u5c06\u8be6\u7ec6\u4ecb\u7ecd\u94c1\u7c89\u7f6e\u6362\u786b\u786b\u9178\u94f6\u7684\u53cd\u5e94\u539f\u7406\u3001\u5e94\u7528\u9886\u57df\u548c\u5bf9\u73af\u5883\u7684\u8003\u8651\u3002<\/p>\n

1.\u53cd\u5e94\u539f\u7406<\/p>\n

\u94c1\u7c89\u7f6e\u6362\u786b\u9178\u94f6\u662f\u7f6e\u6362\u53cd\u5e94\u3002\u8be5\u53cd\u5e94\u4ee5\u94c1\u7c89(Fe)\u4e3a\u8fd8\u539f\u5242\uff0c\u5c06\u786b\u4ee3\u786b\u9178\u94f6(Ag2S2O3)\u4e2d\u7684\u94f6\u79bb\u5b50(Ag+)\u8fd8\u539f\u4e3a\u94f6(Ag)\u3002\u53cd\u5e94\u7684\u5316\u5b66\u5f0f\u5982\u4e0b\u6240\u793a\u3002<\/p>\n

2ag2s2o3 + 3fe\u2192Fe2(S2O3)3 + 4ag\u3002<\/p>\n

\u5728\u8fd9\u4e2a\u53cd\u5e94\u4e2d\uff0c\u786b\u9178\u94f6\u4e2d\u7684\u786b\u79bb\u5b50(s2o32-)\u88ab\u6c27\u5316\u4e3a\u786b\u9178\u79bb\u5b50(hso3-)\uff0c\u94c1\u7c89\u88ab\u6c27\u5316\u4e3a\u94c1(III)\u79bb\u5b50(Fe3+)\u3002\u6700\u7ec8\u751f\u6210\u786b\u9178\u94c1(Fe2(S2O3)3)\u548c\u94f6(Ag)\u3002<\/p>\n

2 .\u5e94\u7528\u9886\u57df\u3002<\/p>\n

\u94c1\u7c89\u7f6e\u6362\u786b\u9178\u94f6\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5206\u6790\u5316\u5b66\u3001\u6709\u673a\u5408\u6210\u3001\u7eaf\u94f6\u7684\u5236\u5907\u7b49\u9886\u57df\u3002\u5728\u5206\u6790\u5316\u5b66\u4e2d\uff0c\u94c1\u7c89\u7f6e\u6362\u786b\u9178\u94f6\u88ab\u7528\u4e8e\u786b\u5316\u7269\u7684\u68c0\u6d4b\u3002\u5728\u6709\u673a\u5408\u6210\u4e2d\uff0c\u94c1\u7c89\u7f6e\u6362\u786b\u9178\u94f6\u7528\u4e8e\u8fd8\u539f\u916e\u548c\u919b\u7b49\u6709\u673a\u5316\u5408\u7269\u3002\u5728\u7eaf\u94f6\u7684\u5236\u5907\u4e2d\uff0c\u94c1\u7c89\u7f6e\u6362\u786b\u786b\u9178\u94f6\u53ef\u7528\u4e8e\u4ece\u542b\u94f6\u5e9f\u6c34\u4e2d\u63d0\u53d6\u7eaf\u94f6\u3002<\/p>\n

3.\u73af\u5883\u4fdd\u62a4\u7684\u610f\u4e49\u3002<\/p>\n

\u94c1\u7c89\u7f6e\u6362\u786b\u786b\u9178\u94f6\u7684\u73af\u4fdd\u610f\u4e49\u4e3b\u8981\u4f53\u73b0\u5728\u5b83\u80fd\u5927\u91cf\u51cf\u5c11\u5e9f\u5f03\u7269\u7684\u4ea7\u751f\uff0c\u540c\u65f6\u8fd8\u80fd\u6709\u6548\u53bb\u9664\u6709\u6bd2\u6709\u5bb3\u7269\u8d28\u3002\u786b\u786b\u9178\u94f6\u5728\u9540\u94f6\u4ea7\u4e1a\u4e2d\u88ab\u5e7f\u6cdb\u7528\u4e8e\u53bb\u9664\u6c61\u67d3\u7269\uff0c\u4f46\u8fd9\u79cd\u65b9\u6cd5\u4f1a\u4ea7\u751f\u5927\u91cf\u7684\u5e9f\u5f03\u7269\uff0c\u9020\u6210\u4e25\u91cd\u7684\u73af\u5883\u6c61\u67d3\u3002\u94c1\u7c89\u7f6e\u6362\u786b\u78fa\u786b\u9178\u94f6\u5c06\u786b\u78fa\u786b\u9178\u94f6\u4e2d\u7684\u94f6\u79bb\u5b50\u8fd8\u539f\u4e3a\u7eaf\u94f6\uff0c\u9632\u6b62\u5e9f\u5f03\u7269\u7684\u4ea7\u751f\u3002\u94c1\u7c89\u65e2\u53ef\u7f6e\u6362\u786b\u4ee3\u786b\u9178\u94f6\u53c8\u53ef\u5c06\u6709\u6bd2\u6709\u5bb3\u7269\u8d28\u8fd8\u539f\u4e3a\u6c30\u5316\u7269\u3001\u786b\u5316\u6c22\u7b49\u65e0\u6bd2\u65e0\u5bb3\u7684\u7269\u8d28\uff0c\u4ece\u800c\u907f\u514d\u5bf9\u73af\u5883\u7684\u6c61\u67d3\u3002<\/p>\n

\u94c1\u7c89\u7f6e\u6362\u786b\u4ee3\u786b\u9178\u94f6\u662f\u4e00\u79cd\u73af\u4fdd\u5316\u5b66\u53cd\u5e94\u65b9\u5f0f\uff0c\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u9886\u57df\u548c\u91cd\u8981\u7684\u73af\u4fdd\u610f\u4e49\u3002\u5728\u672a\u6765\u7684\u53d1\u5c55\u4e2d\uff0c\u6211\u4eec\u6709\u7406\u7531\u76f8\u4fe1\uff0c\u94c1\u7c89\u7f6e\u6362\u786b\u4ee3\u786b\u9178\u94f6\u5c06\u5728\u73af\u4fdd\u9886\u57df\u53d1\u6325\u8d8a\u6765\u8d8a\u91cd\u8981\u7684\u4f5c\u7528\u3002<\/p>\n

\u7898\u5316\u94f6\u4e0e\u94c1\u7c89\u53cd\u5e94<\/h2>\n

<\/p>\n

3\u4ec0\u4e48\u662f\u7898\u5316\u94f6\u548c\u94c1\u7c89\u7684\u53cd\u5e94?<\/p>\n

\u7898\u5316\u94f6\u548c\u94c1\u7c89\u53cd\u5e94\u662f\u6307\u7898\u5316\u94f6\u548c\u94c1\u7c89\u6df7\u5408\u540e\u53d1\u751f\u7684\u5316\u5b66\u53cd\u5e94\u3002\u4e5f\u88ab\u79f0\u4e3a\u94f6\u955c\u53cd\u5e94\u3002<\/p>\n

3\u53cd\u5e94\u7684\u8fc7\u7a0b<\/p>\n

\u53cd\u5e94\u5f00\u59cb\u540e\uff0c\u7898\u5316\u94f6\u6eb6\u4e8e\u6c28\u6c34\uff0c\u5f62\u6210\u6c28\u5316\u5408\u7269\u79bb\u5b50\u3002\u8fd9\u4e2a\u6c28\u5316\u5408\u7269\u79bb\u5b50\u548c\u94c1\u7c89\u53cd\u5e94\u751f\u6210\u6c28\u6c14\u548c\u94f6\u6c89\u6dc0\u3002\u94f6\u6c89\u6dc0\u5728\u94c1\u7c89\u4e0a\u5236\u6210\u94f6\u955c\u3002<\/p>\n

3\u53cd\u5e94\u65b9\u7a0b\u5f0f\u3002<\/p>\n

\u5316\u5b66\u53cd\u5e94\u5f0f\u5982\u4e0b\u3002<\/p>\n

3agi + 2h3\u21923 [Ag(H3)2]+ + I3-\u3002<\/p>\n

Fe + 4 [Ag(H3)2]+ + i3-\u2192Fe3+ + 12h3 + 4ag + 3i –<\/p>\n

3\u5e94\u7528<\/p>\n

\u7898\u5316\u94f6\u548c\u94c1\u7c89\u7684\u53cd\u5e94\u7ecf\u5e38\u88ab\u7528\u4f5c\u5316\u5b66\u53cd\u5e94\u7684\u793a\u8303\u3002\u8fd9\u4e2a\u53cd\u5e94\u4e5f\u88ab\u7528\u4e8e\u94c1\u79bb\u5b50\u7684\u68c0\u6d4b\u3002<\/p>\n

3\u603b\u7ed3<\/p>\n

\u7898\u5316\u94f6\u548c\u94c1\u7c89\u7684\u53cd\u5e94\u662f\u53e4\u8001\u800c\u6709\u8da3\u7684\u5316\u5b66\u53cd\u5e94\u3002\u901a\u8fc7\u8fd9\u4e2a\u53cd\u5e94\uff0c\u53ef\u4ee5\u77e5\u9053\u6c28\u5316\u5408\u7269\u79bb\u5b50\uff0c\u94f6\u6c89\u6dc0\uff0c\u94c1\u79bb\u5b50\u7684\u7279\u6027\u3002\u8fd9\u4e2a\u53cd\u5e94\u4e5f\u88ab\u7528\u4e8e\u94c1\u79bb\u5b50\u7684\u68c0\u6d4b\u3002<\/p>\n

\u94c1\u7c89\u4e0e\u786b\u7c89\u53cd\u5e94\u65b9\u7a0b\u5f0f<\/h2>\n

<\/p>\n

\u77e5\u9053\u94c1\u7c89\u548c\u786b\u78fa\u7c89\u7684\u53cd\u5e94\u65b9\u7a0b\u5f0f\u3002<\/p>\n

\u94c1\u7c89\u548c\u786b\u78fa\u7c89\u7684\u53cd\u5e94\u5f0f\u662f\u5316\u5b66\u4e2d\u7684\u91cd\u8981\u77e5\u8bc6\u3002\u94c1\u7c89\u662f\u5e38\u89c1\u7684\u91d1\u5c5e\uff0c\u800c\u786b\u78fa\u7c89\u662f\u975e\u91d1\u5c5e\u5143\u7d20\u3002\u5b83\u4eec\u4e4b\u95f4\u7684\u53cd\u5e94\u5f0f\u8868\u793a\u7684\u662f\u4e00\u8d77\u53d1\u751f\u7684\u5316\u5b66\u53cd\u5e94\u3002\u4e0b\u9762\u6211\u4eec\u6765\u770b\u94c1\u7c89\u548c\u786b\u78fa\u7c89\u7684\u53cd\u5e94\u5f0f\u3002<\/p>\n

3\u94c1\u7c89\u548c\u786b\u78fa\u7c89\u7684\u5316\u5b66\u53cd\u5e94<\/p>\n

\u94c1\u7c89\u548c\u786b\u78fa\u7c89\u7684\u5316\u5b66\u53cd\u5e94\u662f\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3002\u5728\u8fd9\u4e2a\u53cd\u5e94\u4e2d\uff0c\u94c1\u7c89\u4e2d\u7684\u94c1\u539f\u5b50\u5931\u53bb\u4e00\u90e8\u5206\u7535\u5b50\uff0c\u786b\u78fa\u7c89\u4e2d\u7684\u786b\u539f\u5b50\u5f97\u5230\u7535\u5b50\u3002\u7535\u5b50\u7684\u79fb\u52a8\u4f1a\u5f62\u6210\u786b\u539f\u5b50\u548c\u94c1\u539f\u5b50\u4e4b\u95f4\u7684\u5316\u5b66\u952e\u3002<\/p>\n

\u94c1\u7c89\u548c\u786b\u78fa\u7c89\u7684\u5316\u5b66\u53cd\u5e94\u5f0f\u5982\u4e0b\u3002<\/p>\n

Fe + S\u2192FeS<\/p>\n

\u8fd9\u4e2a\u516c\u5f0f\u4e2dFe\u8868\u793a\u94c1\u7c89\uff0cS\u8868\u793a\u786b\u7c89\uff0cFeS\u8868\u793a\u751f\u6210\u7684\u5316\u5408\u7269\uff0c\u5373\u786b\u5316\u94c1\u3002<\/p>\n

3\u53cd\u5e94\u673a\u7406\u3002<\/p>\n

\u94c1\u7c89\u548c\u786b\u78fa\u7c89\u7684\u53cd\u5e94\u673a\u7406\u5f88\u590d\u6742\u3002\u5f53\u53cd\u5e94\u5f00\u59cb\u65f6\uff0c\u94c1\u7c89\u7684\u8868\u9762\u4f1a\u88ab\u786b\u78fa\u7c89\u8986\u76d6\u3002\u5728\u8fd9\u4e2a\u8fc7\u7a0b\u4e2d\uff0c\u94c1\u539f\u5b50\u4f1a\u5931\u53bb\u4e00\u90e8\u5206\u7535\u5b50\uff0c\u800c\u786b\u539f\u5b50\u4f1a\u5f97\u5230\u7535\u5b50\u3002\u8fd9\u4e9b\u7535\u5b50\u7684\u79fb\u52a8\u4f1a\u5f62\u6210\u786b\u539f\u5b50\u548c\u94c1\u539f\u5b50\u4e4b\u95f4\u7684\u5316\u5b66\u952e\u3002<\/p>\n

\u968f\u7740\u53cd\u5e94\u7684\u8fdb\u884c\uff0c\u751f\u6210\u7684FeS\u5316\u5408\u7269\u5f62\u6210\u4e00\u5c42\u4fdd\u62a4\u819c\uff0c\u9632\u6b62\u94c1\u7c89\u548c\u786b\u78fa\u7c89\u4e4b\u95f4\u7684\u8fdb\u4e00\u6b65\u53cd\u5e94\u3002\u8fd9\u4e2a\u4fdd\u62a4\u819c\u662f\u7531FeS\u5316\u5408\u7269\u5f62\u6210\u7684\uff0c\u5177\u6709\u826f\u597d\u7684\u7a33\u5b9a\u6027\u548c\u8010\u8150\u8680\u6027\u3002<\/p>\n

3\u5e94\u7528\u9886\u57df<\/p>\n

\u94c1\u7c89\u548c\u786b\u78fa\u7c89\u7684\u53cd\u5e94\u65b9\u7a0b\u5f0f\u5728\u5f88\u591a\u9886\u57df\u90fd\u6709\u5e94\u7528\u3002\u4f8b\u5982\uff0c\u5728\u5de5\u4e1a\u4e0a\uff0c\u786b\u5316\u94c1\u662f\u9632\u8150\u6d82\u6599\u548c\u6a61\u80f6\u5236\u54c1\u7b49\u4f7f\u7528\u7684\u91cd\u8981\u6750\u6599\u3002\u786b\u5316\u94c1\u4e5f\u88ab\u7528\u4e8e\u5316\u5b66\u8bd5\u5242\u548c\u836f\u54c1\u7684\u5236\u9020\u3002<\/p>\n

\u94c1\u7c89\u548c\u786b\u78fa\u7c89\u7684\u53cd\u5e94\u8fd8\u53ef\u4ee5\u7528\u4e8e\u6559\u5b66\u548c\u79d1\u7814\u9886\u57df\u3002\u901a\u8fc7\u8c03\u67e5\u8fd9\u4e9b\u53cd\u5e94\u7684\u673a\u5236\u548c\u7279\u6027\uff0c\u53ef\u4ee5\u52a0\u6df1\u5bf9\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u548c\u5316\u5b66\u53cd\u5e94\u52a8\u529b\u5b66\u7684\u7406\u89e3\u3002<\/p>\n

3\u603b\u7ed3<\/p>\n

\u94c1\u7c89\u548c\u786b\u78fa\u7c89\u7684\u53cd\u5e94\u5f0f\u662f\u5316\u5b66\u4e2d\u7684\u91cd\u8981\u77e5\u8bc6\u3002\u901a\u8fc7\u4e86\u89e3\u5316\u5b66\u53cd\u5e94\u7684\u673a\u7406\u548c\u5e94\u7528\u9886\u57df\uff0c\u53ef\u4ee5\u66f4\u597d\u5730\u7406\u89e3\u5316\u5b66\u53cd\u5e94\u7684\u672c\u8d28\u548c\u6027\u8d28\u3002\u540c\u65f6\uff0c\u94c1\u7c89\u548c\u786b\u78fa\u7c89\u7684\u53cd\u5e94\u5f0f\u4e3a\u6211\u4eec\u63d0\u4f9b\u4e86\u4e00\u79cd\u91cd\u8981\u7684\u6750\u6599\u548c\u5316\u5b66\u8bd5\u5242\u7684\u5236\u5907\u9014\u5f84\u3002<\/p>\n

\u6807\u7b7e:\u94c1\u7c89\u548c\u786b\u78fa\u7c89\u7684\u53cd\u5e94\u5f0f\uff0c\u5316\u5b66\u53cd\u5e94\uff0c\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u786b\u5316\u94c1\uff0c\u79d1\u7814\uff0c\u6559\u5b66\uff0c\u5e94\u7528\u9886\u57df\u3002<\/p>\n

\u786b\u9178\u94f6\u600e\u4e48\u7f6e\u6362\u6210\u5355\u8d28\u94f6<\/h2>\n

<\/p>\n

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